The game will kick off at 16.15 CET, ESPN reports.
Madrid play Viktoria Plzen at the Santiago Bernabeu on the Tuesday before the game, as Barca host Inter Milan on Wednesday.
Barcelona last hosted Madrid in May, a week after they clinched the LaLiga title. It ended 1-1.
Both Barca and Madrid have begun the new campaign with three wins from three and sit level at the top of the table.